The Lifecycle and Emission Properties of PAHs in Cosmological Hydrodynamic Galaxy Formation Simulations

We present the first cosmological model for the lifecycle and luminous properties of PAHs in galaxies as they evolve from z=6-->0. We model 40 zoom-in galaxies, coupled with an on-the-fly model for the evolution of dust grains in the ISM. We approximate PAHs as ultrasmall (a < 13 Angstrom) carbonaceous dust grains, and couple this model with single-photon excitation calculations to compute the emergent mid-infrared spectra. (1) If we assume that dust is large upon formation, then PAHs are naturally able to form in situ in the ISM via grain-grain shattering. Interstellar collision velocities increase in low density, diffuse gas in our model; as galaxies evolve, the increase in fractional mass of diffuse gas drives an increase in grain-grain collision velocities and a corresponding rise in the PAH mass fraction (qPAH) from 5 x 10-4 at z 4 to 10-2 at z 0. (2) Increased PAH production in the diffuse ISM results in an inverse relationship between qPAH and the molecular gas fraction. (3) The PAH light-to-mass ratio scales linearly with the radiation field intensity (LPAH/MPAH G 0) but anti-correlates with qPAH, because high-Sigma SFR galaxies have a denser ISM that suppresses shattering. This means the physical qPAH and observed LPAH/LFIR do not evolve in lockstep. (4) The PAH-metallicity relationship (PZR) arises naturally in this framework: galaxies enrich and grow their diffuse ISM fraction simultaneously, linking rising metallicity to rising qPAH. Our models represent the first to reproduce the PZR observed across z=0-2. (5) The LPAH-SFR and LPAH-M mol relations emerge from two effects: more massive galaxies have larger PAH reservoirs, and higher-SFR galaxies excite their PAHs more efficiently per unit mass. Taken together, these results suggest that grain-grain shattering in the diffuse ISM is the main driver behind the evolution of cosmic PAH abundances.