The atomic C/O ratio of KELT-9b

The carbon-to-oxygen (C/O) ratio of a giant planet's atmosphere has long been theorised to hold compositional information that can be traced back to its formation history. Typically, the C/O ratio of an exoplanetary atmosphere is inferred from abundance measurements of major C- and O-bearing molecules such as CO, CO 2, H 2 O, and OH. However, some exoplanets have such elevated temperatures that molecules can be nearly completely thermally dissociated at the pressure levels that observations probe, making it difficult to measure their C/O ratio via these traditional tracers. Here, rather than using molecules, we aim to retrieve the C/O ratio of KELT-9b (T eq = 4000 K) directly from atomic C and O, which are detected in its atmosphere. We analysed two transits of KELT-9b observed with the MAROON-X high-resolution spectrograph, finding absorption cross-correlation signals from atomic C and O as well as refractory metals. From this, we inferred the vertical temperature structure, the relative proportions of volatile and refractory species, and the C/O ratio of KELT-9b using a 1D local thermodynamic equilibrium atmospheric retrieval framework applied only to spectral regions mostly unaffected by non-local thermodynamic equilibrium effects. We measure the atomic C/O ratio of the atmosphere of KELT-9b to be 0.20-0.07+0.13, which is slightly lower than the stellar value of 0.38 plus or minus0.15 and significantly below the solar value of 0.59 plus or minus0.07. We otherwise confirm previous investigations of the terminator region, finding KELT-9b's atmosphere to be thermally inverted and slightly metal-rich. We measure the volatile-to-refractory ratio, a proxy for the ice-to-rock ratio, to be 1.24-0.78+1.93 times solar ([M vol /M ref] = 0.09-0.20+0.19), which is consistent with both KELT-9 and the Sun.