JWST-SUPER I: New insights into irradiated warm Neptunes atmospheres from MIRI observations of HD 106315 c

Sulphur-bearing molecules have recently emerged as powerful tracers of atmospheric photochemistry in exoplanets observed with JWST. In several warm giant planets, SO 2 has been detected as a product of UV-driven chemical processing, suggesting a close connection between stellar irradiation, atmospheric metallicity, and sulphur chemistry. Whether these trends extend to Neptune-mass planets orbiting hotter stars remains largely unexplored. We investigate the atmospheric composition of the warm Neptune HD 106315 c, a Neptune-mass planet orbiting an F-type host star and subjected to a strong ultraviolet (UV) irradiation environment. Here, we report the low-resolution transmission spectrum between 5 and 12 μ m of HD 106315 c obtained with the MIRI Low-Resolution Spectrometer on-board JWST. Our work also includes re-analysis of archival data from HST WFC3 G141 mode of HD 106315 c, as well as contemporaneous XMM and Swift monitoring of the star in the UV and X-ray wavelength ranges. Together with the archival HST WFC3 data, we detect H 2 O and find tentative evidence for NH 3, retrieving abundances of 10 (H 2 O) =-1.40+0.40-0.74 and 10 (NH 3) =-2.47+0.57-0.89, together with an isothermal terminator temperature of 747+150-155 K. We place stringent upper limits on CH 4, SO 2, and CS 2, finding no robust evidence for any sulphur-bearing species despite the intense irradiation received by the planet. The inferred water abundance implies a strongly metal-enriched atmosphere. Elevated intrinsic temperatures can reconcile the non-detections of CH 4 and CS 2 through carbon--sulphur coupling, while the absence of SO 2 points toward a reduced atmospheric sulphur inventory or a near-solar to mildly enhanced C/O ratio, and places HD 106315 c near the transition between sulphur-rich and sulphur-poor chemical regimes.