An ACA map of a molecular cloud interacting with supernova remnant W28

Supernova remnants (SNRs) strongly influence the physical and chemical properties of the molecular clouds (MCs) with which they interact. We carried out a high-resolution observation toward W28F, a chemically rich MC interacting with SNR W28, with the Atacama Compact Array (ACA) in Band 7. Significant emission (> 10 sigma) of CO, CH3OH, p-H2CO, SiO and SO is detected. We reveal the clumpy structures of the shocked MC, with different spatial distributions between CH3OH and SiO. We select six molecular clumps to conduct spectral decomposition and non-local-thermodynamic-equilibrium analysis with the CH3OH and p-H2CO lines. The best-fit results show a H2 density of nH2 (1-3) * 10 5 cm-3 and a gas temperature of Tgas 50-170 K in most of the fitted components. The H2 density and gas temperature show a clear anti-correlation across different regions, with the thermal pressure consistent with that of the adjacent X-ray-emitting hot plasma. This is consistent with the picture that the SNR shocks propagate into multi-phase gas, with a pressure balance existing between different phases. We propose that the high abundance ratio between E-CH3OHand A-CH3OH (> 0.9) suggests extra gas-phase processes to enhance this ratio, such as proton exchange with H3+ and HCO+. The chemical segregation between CH3OH and SiO, in both the spatial and spectral regime, can be explained by the fact that CH3OH traces slow shocks while SiO traces fast shocks.