New 12C/13C and 14N/15N isotopic ratio measurements in Jupiter's stratosphere revealed by ALMA

The collision of comet SL9 with Jupiter in 1994 changed the chemical composition of the Jovian stratosphere for decades. New molecules were detected minutes after the impacts (HCN, CO, CS, etc.) and some are still present today. They were deposited in the stratosphere at pressures lower than 0.1 mbar and were most probably formed by shock-induced chemistry recombining Jovian and cometary material. However, the question of the origin of these molecules is still not completely understood. One way to address this open question is to determine the isotopic composition of the new molecules. Isotopic ratios have long been measured in the Solar System. They present a variety of values depending on the object or the molecule and therefore trace different reservoirs of material. Derivations of carbon and nitrogen isotopic ratios in HCN four years after SL9 showed atypical depletions in the heavier isotopes that had never been observed before in the Solar System. These results suggested an unusual cometary composition or an unknown fractionation mechanism in the hot and shocked air parcels. We aim to measure carbon and nitrogen isotopic ratios in HCN to shed light on the puzzling results of 1998. With Atacama Large Millimeter/submillimeter Array data from 2017 and radiative-transfer calculations, we derived the abundance of two HCN isotopologues, H13CN and HC15N, at pressures probed from 0.03 to 1.8 mbar. We find 12C/13C = 73 plus or minus5 and 14N/15N = 245 plus or minus29, respectively (0.76-0.87) and (0.80-1.00) times the terrestrial references, and (0.69-0.87) and (0.42-0.70) times the solar-Jovian bulk values. In contrast to the strong depletions reported in 1998, our values are instead compatible with an enrichment in the heavier isotopes relative to the Jovian bulk. We interpret these enrichments as the direct signature of the cometary contribution in HCN and/or as 23 years of chemical evolution.